Nanoteknoloji ile Su Arıtma ve Atık Yönetimi
Özet
Sanayileşme, artan nüfus miktarı, patojen mikroorganizmalar, endüstriyel kimyasal bileşikler, ağır metaller ve içme suyunun miktarının azalmasına gibi nedenlerle sucul ekosistemlerin kirlenmesi ve su kaynaklarının azalması günümüzdeki önemli sorunlardandır. Bu nedenle, suyun geri dönüşümünde atık su sistemlerine büyük pay düşmektedir. Gelenekse atık su arıtma yöntemleri her ne kadar Dünya’nın birçok yerinde yaygın olarak kullanılsa da teknolojinin gelişmesi ile nanomalzemeler de atık su arıtma yöntemleri arasına girmiştir. Nanomalzemelere dayalı bu sistemler atık su yönetimini iyileştirmekte olup nanoteknolojinin çalışma alanlarından birini oluşturmaktadır. Bu kitap bölümünde, atık su tesislerinde kullanılan nanofiltrasyon membranları, nanoadsorbanlar, nanokatalizörler ve fotokataliz, antibakteriyel nanomalzemeler açıklanmıştır. İlerleyen teknolojik sistemler ile bu yöntemlerin kullanılmasının dünya çapında olabileceği ve yeni nanomalzemelerin geliştirileceği düşünülmektedir.
Due to reasons such as industrialization, increasing population, pathogenic microorganisms, industrial chemical compounds, heavy metals and the decrease in the amount of drinking water, the pollution of aquatic ecosystems and the decrease in water resources are important problems today. Therefore, wastewater systems have a large share in the recycling of water. Although traditional wastewater treatment methods are widely used in many wastewaters, nanomaterials have also entered the wastewater treatment methods with the development of technology. These systems based on nanomaterials improve wastewater management and constitute one of the fields of study of nanotechnology. In this book section, nanofiltration membranes, nanoadsorbents, nanocatalysts and photocatalysis, antibacterial nanomaterials used in wastewater facilities are explained. It is thought that with advancing technological systems, the use of these methods can be worldwide, and new nanomaterials will be developed.
Referanslar
Türkiye Su Enstitüsü (2025). Erişim adresi: https://suen.gov.tr/Suen/catdty.aspx?val=16561 [Erişim Tarihi: 1 Haziran 2025]
Singh A, Pratap SG, Raj A. Occurrence and dissemination of antibiotics and antibiotic resistance in aquatic environment and its ecological implications: a review. Environmental Science and Pollution Research. 2024; 31(35): 47505-47529. doi: 10.1007/s11356-024-34355-x
Duong LTK, Nguyen TTT, Van Tran T. Combined pollution of tetracyclines and microplastics in the aquatic environment: insights into the occurrence, interaction mechanisms and effects. Environmental Research. 2024; 120223. doi: 10.1016/j.envres.2024.120223
Włodarczyk-Makuła M. Selected organic micropollutants in the aquatic environment. Desalination and Water Treatment. 2024; 317: 100061. doi: 10.1016/j.dwt.2024.100061
Rathi BS, Kumar PS. Application of adsorption process for effective removal of emerging contaminants from water and wastewater. Environmental Pollution. 2021; 280: 116995. doi: 10.1016/j.envpol.2021.116995
Singh K K, Singh A, Rai S. A study on nanomaterials for water purification. Materials Today: Proceedings. 2022; 51: 1157–1163.
UN, 2024. Progress on Level of Water Stress – 2024 Update https://www.unwater.org/publications/progress-level-water-stress-2024-update
Baskar AV, Bolan N, Hoang SA, et al. Recovery, regeneration and sustainable management of spent adsorbents from wastewater treatment streams: a review. Science of the Total Environment. 2022; 822: 153555. doi: 10.1016/j.scitotenv.2022.153555
Morin-Crini N, Lichtfouse E, Fourmentin M, et al. Removal of emerging contaminants from wastewater using advanced treatments. A review. Environmental Chemistry Letters. 2022; 20(2): 1333–1375. doi: 10.1007/s10311-021-01379-5
Sikiru S, Ayodele OA, Sanusi YK, et al. A comprehensive review on nanotechnology application in wastewater treatment a case study of metal-based using green synthesis. Journal of Environmental Chemical Engineering. 2022; 10: 108065. doi: 10.1016/j.jece.2022.108065
Pérez H, Quintero García OJ, Amezcua-Allieri MA, et al. Nanotechnology as an efficient and effective alternative for wastewater treatment: an overview. Water Science and Technology. 2023; 87(12): 2971-3001. doi: 10.2166/wst.2023.179
Ottoson J, Hansen A, Björlenius B, et al. Removal of viruses, parasitic protozoa and microbial indicators in conventional and membrane processes in a wastewater pilot plant. Water Research. 2006; 40(7): 1449-1457. doi: 10.1016/j.watres.2006.01.039
Stasinakis AS, Thomaidis NS. Fate and biotransformation of metal and metalloid species in biological wastewater treatment processes. Critical Reviews in Environmental Science and Technology, 2010; 40(4): 307-364. doi: 10.1080/10643380802339026
Köck-Schulmeyer M, Villagrasa M, de Alda ML, et al. Occurrence and behavior of pesticides in wastewater treatment plants and their environmental impact. Science of The Total Environment. 2013; 458: 466-476. doi: 10.1016/j.scitotenv.2013.04.010
Liu ZH, Kanjo Y, Mizutani S. Removal mechanisms for endocrine disrupting compounds (EDCs) in wastewater treatment—physical means, biodegradation, and chemical advanced oxidation: a review. Science of The Total Environment. 2009; 407(2): 731-748. doi: 10.1016/j.scitotenv.2008.08.039
Nassiri Koopaei N, Abdollahi M. Health risks associated with the pharmaceuticals in wastewater. DARU Journal of Pharmaceutical Sciences. 2017; 25(1): 9. doi: 10.1186/s40199-017-0176-y
Wlodarczyk-Makula M. The loads of PAHs in wastewater and sewage sludge of municipal treatment plant. Polycyclic Aromatic Compounds. 2005; 25(2): 183-194. doi: 10.1080/10406630590930743
Camacho-Muñoz D, Martín J, Santos, JL, Aparicio I, et al. Occurrence of surfactants in wastewater: hourly and seasonal variations in urban and industrial wastewaters from Seville (Southern Spain). Science of the Total Environment. 2014; 468: 977-984. doi: 10.1016/j.scitotenv.2013.09.020
Fernández C, Larrechi MS, Callao MP. An analytical overview of processes for removing organic dyes from wastewater effluents. TrAC Trends in Analytical Chemistry, 2010; 29(10): 1202-1211. doi: 10.1016/j.trac.2010.07.011
Pendergast MM, Hoek EM. A review of water treatment membrane nanotechnologies. Energy & Environmental Science, 2011; 4(6): 1946-1971. doi: 10.1039/C0EE00541J
Qu X, Alvarez PJ, Li Q. Applications of nanotechnology in water and wastewater treatment. Water Research, 2013; 47(12): 3931-3946. doi: 10.1016/j.watres.2012.09.058
Iravani S. Nanomaterials and nanotechnology for water treatment: recent advances. Inorganic and Nano-Metal Chemistry, 2021; 51(12): 1615-1645. doi: 10.1080/24701556.2020.1852253
Nasrollahzadeh M, Sajjadi M, Iravani S, et al. Carbon-based sustainable nanomaterials for water treatment: state-of-art and future perspectives. Chemosphere. 2021; 263: 128005. doi: 10.1016/j.chemosphere.2020.128005
Epelle EI, Okoye PU, Roddy S, et al. Atıksu Arıtımı için Nanomalzemelerin Uygulamalarındaki Gelişmeler. Çevreler. 2022; 9 (11), 141. doi: 10.3390/environments9110141
Resmî Gazete Tarihi: 31.12.2004 Resmî Gazete Sayısı:25687 ; (https://www.mevzuat.gov.tr/mevzuat?MevzuatNo=7221&MevzuatTur=7&MevzuatTertip=5)
Elgallal M, Fletcher L, Evans B. Assessment of potential risks associated with chemicals in wastewater used for irrigation in arid and semiarid zones: a review. Agricultural Water Management. 2016; 177: 419–431. doi: 10.1016/j.agwat.2016.08.027
Jones ER, van Vliet MTH, Qadir M, et al. Countrylevel and gridded estimates of wastewater production, collection, treatment and reuse. Earth System Science Data. 2021; 13(2): 237–54. doi: 10.5194/essd-13-237-2021
Nishat A, Yusuf M, Qadir A, et al. Wastewater treatment: A short assessment on available techniques. Alexandria Engineering Journal. 2023; 76: 505-516. doi: 10.1016/j.aej.2023.06.054.
Ademiluyi FT, Amadi SA, Amakama NJ. Adsorption and Treatment of Organic Contaminants using Activated Carbon from Waste Nigerian Bamboo. Journal of Applied Sciences and Environmental Management. 2009; 13(3). doi: 10.4314/jasem.v13i3.55351
Pavithra KG, Jaikumar VJJOI. Removal of colorants from wastewater: A review on sources and treatment strategies. Journal of Industrial and Engineering Chemistry. 2019; 75: 1-19. doi: 10.1016/j.jiec.2019.02.011
Mandal T, Maity S, Dasgupta D, et al. Advanced oxidation process and biotreatment: Their roles in combined industrial wastewater treatment. Desalination. 2010; 250(1): 87-94. doi: 10.1016/j.desal.2009.04.012
Krishnan S, Rawindran H, Sinnathambi CM, et al. Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants. In IOP Conference Series: Materials Science and Engineering 2017; 206(1): 012089).
Rahmanlar M. (2017). Atık su Arıtma Tesisleri için Uygun Bir İşletim Yönetim Model Önerisi, T.C. Kalkınma Bakanlığı Yayın No: 2975, 191 s.
Alizad Oghyanous F. (2022). Nanoparticles in Wastewater Treatment. IntechOpen. doi: 10.5772/intechopen.100239
Shannon MA, Bohn PW, Elimelech M, et al. Science and technology for water purification in the coming decades. Nature. 2008; 452(7185): 301-310. doi: 10.1038/nature06599
Ying Y, Ying W, Li Q, et al. Recent advances of nanomaterial-based membrane for water purification, Applied Material Today. 2017; 7: 144–158. doi: 10.1016/j.apmt.2017.02.010
Thines RK, Mubarak NM, Nizamuddin S, et al. Application potential of carbon nanomaterials in water and wastewater treatment: a review. Journal of the Taiwan Institute of Chemical Engineers. 2017; 72: 116–133. doi: 10.1016/j.jtice.2017.01.018
Zhu J, Hou J, Zhang Y, et al. Polymeric antimicrobial membranes enabled by nanomaterials for water treatment. Journal of Membrane Science. 2018; 550: 173–197. doi: 10.1016/j.memsci.2017.12.071
Mansouri J, Charlton T, Chen V, et al. Biofouling performance of silver-based PES ultrafiltration membranes. Desalination and Water Treatment. 2016; 57(58): 28100–28114. doi: 10.1080/19443994.2016.1183231
Sarkar S, Sarkar A, Bhattacharjee C. 2017 Nanotechnology-Based Membrane-Separation Process for Drinking Water Purification. Academic Press, London, UK.
Bystrzejewska-Piotrowska G, Golimowski J, Urban PL. Nanoparticles: their potential toxicity, waste and environmental management. Waste Management. 2009; 29(9): 2587–2595. doi: 10.1016/j.wasman.2009.04.001
Zhao G, Li J, Ren X, et al. Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environmental Science & Technology. 2011; 45(24): 10454-10462. doi: 10.1021/es203439v
Anjum M, Miandad R, Waqas M, et al. Remediation of wastewater using various nano-materials. Arabian Journal of Chemistry. 2019; 12: 4897–4919. doi: 10.1016/j.arabjc.2016.10.004
Innovations in Nanotechnology for Waste Water Treatment T. H. and Mohanadoss Ponraj. 2022. Prof. Ramasamy Subbaiya, Dr. Sivasubramanian Manikandan. Emerging Technologies and Advanced Techniques for Waste Treatment and Energy Production. doi: 10.20546/978-93-94174-07-8
Nasir S, Hussein MZ, Zainal Z, et al. Carbon-Based Nanomaterials/Allotropes: A Glimpse of Their Synthesis, Properties and Some Applications. Materials. 2018; 11: 295. doi: 10.3390/ma11020295
Sayed ET, Alawadhi H, Elsaid K, et al. A Carbon-Cloth Anode Electroplated with Iron Nanostructure for Microbial Fuel Cell Operated with Real Wastewater. Sustainability. 2020; 12: 6538. doi: 10.3390/su12166538
Ray SS, Gusain R, Kumar N. Carbon Nanomaterial-Based Adsorbents for Water Purification: Fundamentals and Applications; Elsevier: Amsterdam, The Netherlands, 2020.
Jain K, Patel AS, Pardhi VP, et al. Nanotechnology in wastewater management: a new paradigm towards wastewater treatment. Molecules. 2021; 26(6): 1797. doi: 10.3390/molecules26061797
Abou-Shanab RA, Ji M-K, Kim H-C, et al. Microalgal species growing on piggery wastewater as a valuable candidate for nutrient removal and biodiesel production. The Journal of Environmental Management. 2013; 115: 257–264. doi: 10.1016/j.jenvman.2012.11.022
Morones JR, Elechiguerra JL, Camacho A, et al. The bactericidal effect of silver nanoparticles. Nanotechnology. 2005; 16(10): 2346. doi: 10.1088/0957-4484/16/10/059
Khajeh M, Sanchooli E. Synthesis and evaluation of silver nanoparticles material for solid phase extraction of cobalt from water samples. Applied Nanoscience. 2011; 1: 205209. doi: 10.1007/s13204-011-0028-x
Mehrizad A, Zare K, Dashti KH, et al. Kinetic and thermodynamic studies of adsorption of 4-chloro-2-nitrophenol on nanoTiO2. JPTC. 2011; 8: 33–37.
Tyagi I, Gupta V, Sadegh H, et al. Nanoparticles as adsorbent; a positive approach for removal of noxious metal ions: A review. Science, Technology and Development Journal. 2017; 34: 195–214.
Ray PC. Size and shape dependent second order nonlinear optical properties of nanomaterials and their application in biological and chemical sensing. Chemical Reviews. 2010; 110: 5332–5365. doi: 10.1021/cr900335q
Gupta AK, Ghosal PS, Dubey BK. Hybrid nanoadsorbents for drinking water treatment: A critical review. Hybrid Nanomaterials: Advances in Energy, Environment, and Polymer Nanocomposites. 2017; 199. doi: 10.1002/9781119160380.ch4
Najafpoor A, Norouzian-Ostad R, Alidadi H, et al. Effect of magnetic nanoparticles and silver-loaded magnetic nanoparticles on advanced wastewater treatment and disinfection. Journal of Molecular Liquids. 2020; 303: 112640. doi: 10.1016/j.molliq.2020.112640
Ali I, Peng C, Naz I, et al. Phytogenic magnetic nanoparticles for wastewater treatment: a review. RSC Advances. 2017; 7(64): 40158-40178. doi: 10.1039/C7RA04738J
Daraei H, Amrane A, Kamali, H. Assessment of phenol removal efficiency by synthesized zero iron nanoparticles and Fe powder using the response surface methodology. Iranian Journal of Chemistry and Chemical Engineering (IJCCE). 2017; 36(3), 137-146. doi: 10.30492/ijcce.2017.28071
Tran N. Mir A, Mallik D, et al. Bactericidal effect of iron oxide nanoparticles on Staphylococcus aureus. International Journal of Nanomedicine. 2010; 277-283. doi: 10.2147/ijn.s9220
Sachse C, Weiß N, Gaponik N, et al. ITO‐free, small‐molecule organic solar cells on spray‐coated copper‐nanowire‐based transparent electrodes. Advanced Energy Materials. 2014; 4(2): 1300737. doi: 10.1002/aenm.201300737
Ghaseminezhad SM, Shojaosadati SA. Evaluation of the antibacterial activity of Ag/Fe3O4 nanocomposites synthesized using starch. Carbohydrate Polymers. 2016; 144: 454-463. doi: 10.1016/j.carbpol.2016.03.007
Azócar MI, Alarcón R, Castillo A, et al. Capping of silver nanoparticles by anti-inflammatory ligands: antibacterial activity and superoxide anion generation. Journal of Photochemistry and Photobiology B: Biology. 2019; 193: 100-108. doi: 10.1016/j.jphotobiol.2019.02.005
Ghaseminezhad SM, Shojaosadati SA, Meyer RL. Ag/Fe3O4 nanocomposites penetrate and eradicate S. aureus biofilm in an in vitro chronic wound model. Colloids and Surfaces B: Biointerfaces. 2018; 163: 192-200. doi: 10.1016/j.colsurfb.2017.12.035
Davoudi M, Ehrampoush MH, Vakili T, et al. Antibacterial effects of hydrogen peroxide and silver composition on selected pathogenic enterobacteriaceae. International Journal of Environmental Health Engineering. 2012; 1(1): 23. doi: 10.4103/2277-9183.96148